Product ID:2250/2252 MS-180/CO2 FREON TF SOLVENT
MSDS Date:03/01/1991
FSC:6830
NIIN:00F039156
MSDS Number: BWWKK

MILLER-STEPHENSON CHEMICAL CO

55 BACKUS AVE/GEORGE WASHINGTON HWY
DANBURY, CT 06810-5000
US

Emergency Phone: 203-743-2212/203-743-4447

Info Phone: 203-743-2212/203-743-4447

Cage: 18598

MILLER-STEPHENSON CHEMICAL CO INC

950 DANBURY, CT 06810 US

Telephone: 203-743-4447

Cage: 18598

FREON 113, 1,1,2,-TRICHLORO-1,2,2,-TRIFLUOROETHANE,

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 96.3%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 3.7%

OSHA PEL 5000 PPM

ACGIH TLV: 9000 MG/CUM

LD50 LC50 Mixture:ORAL LD50(RATS): 43000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: VAPOR IS > THAN AIR & CAN
REDUCE OXYGEN FOR BREATHING. BREATHING HIGH CONCENTRATIONS OF VAPOR
MAY CAUSE NARCOSIS, CARDIAC IRREGULARITIES/DEATH. SKIN: REPEATED
CONTACT CAN CAUSE IRRITATION. PRODUCT IS POORLY ABSORBED.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, LIGHT HEADEDNESS, GIDDINESS,
SHORTNESS OF BREATH, NARCOSIS, SUFFOCATION, DISCOMFORT,
UNCONSCIOUSNESS, DEFATTING.
Medical Cond Aggravated by Exposure:CARDIOVASCULAR DISEASE: EXPOSURE AT
APPROXIMATELY 5000 PPM & ABOVE, FOLLOWED BY A LARGE INTRAVENOUS
EPINEPHRINE CHALLENGE, HAS INDUCED SERIOUS CARDIAC IRREGULARITIES.

First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED.
DON'T GIVE EPINEPHRINE/SIMILAR DRUGS. EYES: IMMEDIATELY FLUSH
W/PLENTY OF WATER FOR 15 MINS. SKIN: FLUSH W/WATER. INGESTION:
DON'T INDUCE VO MITING. ASPIRATION HAZARD. OBTAIN MEDICAL ATTENTION
IN ALL CASES. (SEE SUPP)

Flash Point Method:TOC
Flash Point:NONE
Fire Fighting Procedures:WEAR SCBA.
Unusual Fire/Explosion Hazard:PRESSURIZED AEROSOL CONTAINERS AT
ELEVATED TEMPS MAY VENT, RUPTURE/BURST & ADD TO FLYING & FALLING
DEBRIS.

Spill Release Procedures:VENTILATE AREA. REMOVE OPEN FLAMES/RED HOT
SURFACES. ALLOW TO EVAPORATE. SCBA IS REQUIRED FOR LARGE SPILLS.

Handling and Storage Precautions:DON'T STORE NEAR SOURCES OF HEAT, IN
DIRECT SUNLIGHT/WHERE TEMPS EXCEED 120F. ROTATE STOCK TO SHELF LIFE
OF ONE YEAR. USE IN WELL VENTILATED AREA.
Other Precautions:DON'T PUNCTURE/DAMAGE CONTAINERS. DON'T
PUNCTURE/INCINERATE AEROSOL CANS. DON'T SPRAY LIQUID ON SKIN. AVOID
BREATHING VAPORS & PROLONGED SKIN EXPOSURE. AVOID INGESTION.

Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS NO
RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.
Ventilation:LOCAL EXHAUST: USE WHEN LARGE AMOUNTS ARE RELEASED.
MECHANICAL (GENERAL): TO BE USED IN LOW PLACES.
Protective Gloves:BUTYL
Eye Protection:CHEMICAL SPLASH GOGGLES
Supplemental Safety and Health
NOTE TO PHYSICIAN: BECAUSE OF POSSIBLE INCREASED RISK OF ELICITING
CARDIAC DYSRYTHMIAS, CATECHOLAMINE DRUGS, SUCH AS EPINEPHRINE
SHOULD BE CONSIDERED ONLY AS A LAST RESORT IN LIFE THREATENING
EMERGENC IES.

Boiling Pt:B.P. Text:118F
Vapor Pres:334
Vapor Density:2.9
pH:7
Evaporation Rate & Reference:(SEE SUPP)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR & COLORLESS LIQUID W/FAINT SOLVENT ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI/ALKALINE EARTH METALS
Stability Condition to Avoid:ELEVATED TEMPS, OPEN FLAMES, RED HOT
SURFACES, TEMPS > 120F.
Hazardous Decomposition Products:HYDROCHLORIC & HYDROFLUORIC
ACIDS-POSSIBLE CARBONYL HALIDES.

Waste Disposal Methods:BEFORE DISPOSING OF CAN, CONTINUE TO EXPEL THE
GAS PROPELLANT FOR APPROXIMATELY 30 SECONDS UNTIL THE CAN IS EMPTY.
DISPOSAL SERVICE TO LANDFIL IAW/FEDERAL, STATE & LOCAL REGULATIONS.
DON'T PUNTURE/INC INERATE AEROSOL CANS. UN1956.

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expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
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particular situation.